Stress-structure relation in dense colloidal melt under forward and instantaneous reversal of shear

Dense supercooled colloidal melt in forward shear from a quiescent state shows overshoot in shear stress at 10% strain with an unchanged fluid structure at equal stress before and after overshoot. In addition, we find overshoot in normal stress with a monotonic increase in osmotic pressure at an identical strain. The first and second normal stress become comparable in magnitude and opposite in sign. Functional dependence of the steady state stress and osmotic pressure with Peclet number demonstrate signature of crossover between Newtonian and nearly- Newtonian regime. Moreover, instantaneous shear reversal from steady state exhibit Bauschinger effect, where strong history dependence is observed depending on the time of flow reversal. The distribution of particulate stress and osmotic pressure at the point of flow reversal is shown to be a signature of the subsequent response. We link the history dependence of the stress-strain curves to changes in the fluid structure measured through the angular components of the radial distribution function. A uniform compression in transition from forward to reversed flowing state is found.Comment: 8 pages, 6 figure

Controlling motile disclinations in a thick nematogenic material with an electric field

Manipulating topological disclination networks that arise in a symmetry-breaking phase transfor- mation in widely varied systems including anisotropic materials can potentially lead to the design of novel materials like conductive microwires, self-assembled resonators, and active anisotropic matter. However, progress in this direction is hindered by a lack of control of the kinetics and microstructure due to inherent complexity arising from competing energy and topology. We have studied thermal and electrokinetic effects on disclinations in a three-dimensional nonabsorbing nematic material with a positive and negative sign of the dielectric anisotropy. The electric flux lines are highly non-uniform in uniaxial media after an electric field below the Fr\'eedericksz threshold is switched on, and the kinetics of the disclination lines is slowed down. In biaxial media, depending on the sign of the dielectric anisotropy, apart from the slowing down of the disclination kinetics, a non-uniform electric field filters out disclinations of different topology by inducing a kinetic asymmetry. These results enhance the current understanding of forced disclination networks and establish the pre- sented method, which we call fluctuating electronematics, as a potentially useful tool for designing materials with novel properties in silico.Comment: 17 Pages, 14 Figure

Development of Multiport Single Stage Bidirectional Converter for Photovoltaic and Energy Storage Integration

The energy market is on the verge of a paradigm shift as the emergence of renewable energy sources over traditional fossil fuel based energy supply has started to become cost competitive and viable. Unfortunately, most of the attractive renewable sources come with inherent challenges such as: intermittency and unreliability. This is problematic for today\u27s stable, day ahead market based power system. Fortunately, it is well established that energy storage devices can compensate for renewable sources shortcomings. This makes the integration of energy storage with the renewable energy sources, one of the biggest challenges of modern distributed generation solution. This work discusses, the current state of the art of power conversion systems that integrate photovoltaic and battery energy storage systems. It is established that the control of bidirectional power flow to the energy storage device can be improved by optimizing its modulation and control. Traditional multistage conversion systems offers the required power delivery options, but suffers from a rigid power management system, reduced efficiency and increased cost. To solve this problem, a novel three port converter was developed which allows bidirectional power flow between the battery and the load, and unidirectional power flow from the photovoltaic port. The individual two-port portions of the three port converter were optimized in terms of modulation scheme. This leads to optimization of the proposed converter, for all possible power flow modes. In the second stage of the project, the three port converter was improved both in terms of cost and efficiency by proposing an improved topology. The improved three port converter has reduced functionality but is a perfect fit for the targeted microinverter application. The overall control system was designed to achieve improved reference tracking for power management and output AC voltage control. The bidirectional converter and both the proposed three port converters were analyzed theoretically. Finally, experimental prototypes were built to verify their performance